Surface Decomposition of Doped PrBaMn<sub>2</sub>O<sub>5+δ</sub> Induced by <i>In Situ</i> Nanoparticle Exsolution: Quantitative Characterization and Catalytic Effect in Methane Dry Reforming Reaction

نویسندگان

چکیده

The exsolution of metallic nanoparticles (NPs) from perovskite oxides is a promising strategy for synthesizing supported catalysts. associated segregation A-site cations on the surface challenging to investigate experimentally and often detrimental catalytic performance. In this work, we found that during in situ Ni-Co bimetallic Pr0.45Ba0.45Mn1–x(Co1/3 Ni2/3)xO3±δ, cation enrichment occurred when x 0.1; yet, decomposed reached 0.2, forming thin layer comprising various nanocrystalline oxides, which partially blocked active sites exsolved particles. A hydration carbonation reaction facilitated conversion BaO species into large highly crystallized BaCO3 This enabled exposure more offered chance quantify accounts ∼7.2 wt % total perovskite. Because unique feature, surface-decomposed catalyst showed higher activity dry methane reforming with better stability. Importantly, regeneration feature was not hampered as complete exsolution-dissolution recyclability remained.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Investigation of the catalytic performance and coke formation of nanocrystalline Ni/SrO-Al2O3 catalyst in dry reforming of methane

In this study, nickel catalysts supported on mesoporous nanocrystalline gamma alumina promoted by various strontium contents were prepared by the impregnation method and employed in dry reforming of methane (DRM). The prepared catalysts were characterized using N2 adsorption (BET), temperature-programmed reduction and oxidation (TPR,) and oxidation (TPDTPO), X-ray diffraction (XRD), and scannin...

متن کامل

Dry reforming of methane under an electro-catalytic bed: effect of electrical current and catalyst composition

Dry reforming of methane (DRM) has been investigated under an electronactivated catalytic bed in a thermo-electrical reactor. The main objective of this work was to investigate what the impact of the electrical current on the conversion of methane is. The combination of thermal and electrical energy allowed achieving higher conversions for both reactants at temperatures varying from 850–950°C. ...

متن کامل

Dry Reforming of Methane Using Cold Plasma; Kinetic Model Study

In this work, the dry reforming of methane was studied using a corona and gliding discharge plasma microreactors. A chemical kinetic model was developed to describe the experimental behavior observed. The kinetic model is proposed based on the assumption that the reactant molecules CH4 or CO2 are attacked by active species produced b...

متن کامل

An Investigation into the Effect of Hydrotalcite Calcination Temperature on the Catalytic Performance of Mesoporous Ni-MgO-Al2O3 Catalyst in the Combined Steam and Dry Reforming of Methane

Several mesoporous nickel-based catalysts with MgO-Al2O3 as the catalyst support were prepared using a co-precipitation method at a constant pH. The supports were prepared from the decomposition of an Mg-Al hydrotalcite-like structure which had already been prepared with Mg/Al=1. Prior to impregnating 10 wt.% nickel on the supports, the precursor was decomposed at several ...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Chemistry of Materials

سال: 2022

ISSN: ['1520-5002', '0897-4756']

DOI: https://doi.org/10.1021/acs.chemmater.2c02488