Surface Decomposition of Doped PrBaMn<sub>2</sub>O<sub>5+δ</sub> Induced by <i>In Situ</i> Nanoparticle Exsolution: Quantitative Characterization and Catalytic Effect in Methane Dry Reforming Reaction
نویسندگان
چکیده
The exsolution of metallic nanoparticles (NPs) from perovskite oxides is a promising strategy for synthesizing supported catalysts. associated segregation A-site cations on the surface challenging to investigate experimentally and often detrimental catalytic performance. In this work, we found that during in situ Ni-Co bimetallic Pr0.45Ba0.45Mn1–x(Co1/3 Ni2/3)xO3±δ, cation enrichment occurred when x 0.1; yet, decomposed reached 0.2, forming thin layer comprising various nanocrystalline oxides, which partially blocked active sites exsolved particles. A hydration carbonation reaction facilitated conversion BaO species into large highly crystallized BaCO3 This enabled exposure more offered chance quantify accounts ∼7.2 wt % total perovskite. Because unique feature, surface-decomposed catalyst showed higher activity dry methane reforming with better stability. Importantly, regeneration feature was not hampered as complete exsolution-dissolution recyclability remained.
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ژورنال
عنوان ژورنال: Chemistry of Materials
سال: 2022
ISSN: ['1520-5002', '0897-4756']
DOI: https://doi.org/10.1021/acs.chemmater.2c02488